Authors: J. Fochtmann, C. Peters, R. Fernández, R. Lucklum, D. McCann, J. Vetelino, A. Arnau

Journal: Sensors and actuators B: Chemical (2012)

 

Investigating the electrical sensitivity of lateral field excited resonators (LFE) we observed two characteristics to highly impact sensitivity. First, an increase of the piezoelectric coupling factor k enhances the viscosity measurement range. Higher coupling factors are provided by the use of new materials, namely lithium tantalite (LiTaO3) and lithium niobate (LiNbO3) with coupling factors of 0.43 and 0.91 respectively. Since the sensitivity to electrical load parameters is governed by relative permittivity of the resonator material itself, the sensitivity to electrical parameters is found to decrease for new materials. Second, an electrode pattern that reveals higher energy trapping in the center of crystal was investigated. Compared to common LFE pattern, a third electrode was introduced in center between bite wing electrodes. Finite element modeling in ANSYS© shows enhanced sensitivity to low relative permittivity in range from 1 to 8. We performed experiments to verify the simulation results. Although an increased frequency shift compared to common LFE resonators was not observed, significantly higher conductance amplitudes occurred, which enhances the measurement range to high viscosity liquids, too.

Authors: Y. Montagut, J.V. García, Y. Jiménez, C. March, A. Montoya, A. Arnau

Journal: Review of Scientific Instruments (2011)

 

The improvement of sensitivity in quartz crystal microbalance (QCM) applications has been addressed in the last decades by increasing the sensor fundamental frequency, following the increment of the frequency/mass sensitivity with the square of frequency predicted by Sauerbrey. However, this sensitivity improvement has not been completely transferred in terms of resolution. The decrease of frequency stability due to the increase of the phase noise, particularly in oscillators, made impossible to reach the expected resolution. A new concept of sensor characterization at constant frequency has been recently proposed. The validation of the new concept is presented in this work. An immunosensor application for the detection of a low molecular weight contaminant, the insecticide carbaryl, has been chosen for the validation. An, in principle, improved version of a balanced-bridge oscillator is validated for its use in liquids, and applied for the frequency shift characterization of the QCM immunosensor application. The classical frequency shift characterization is compared with the new phase-shift characterization concept and system proposed.

Authors: Ilya Reviakine, Diethelm Johannsmann and Ralf P. Richter

Journal: Analytical Chemistry, 2011

Authors: R. Torres, Y. Jiménez, A. Arnau, C. Gabrielli, S. Joiret, H. Perrot, T.K.L. To, X. Wang

Journal: Electrochimica Acta (2010)

For many years, polyaniline films have appeared to be one of the most studied conducting polymers. At the same time, ac-electrogravimetry has been used as a powerful technique for different polymer films but in general for slow perturbation rates. Two reasons for that: on the one hand, high frequency mass transfer responses are not expected and on the other hand, the electronic interfaces dedicated for ac-electrogravimetry are not prepared to follow, without distortion, high rate frequency shifts, faster than a few hertz. This paper shows that high ionic transfer responses can be detected by using a new ac-electrogravimetry concept. The experiments conducted with PANI tried to verify whether high frequency responses in conducting polymers are possible or not. The main interest of the new device is to reach the high frequency values directly and to demonstrate an ionic transfer contribution at 1 kHz which was not predicted with old systems.

Authors: A. Arnau, Y. Montagut, J.V. García, Y. Jiménez

Journal: Meas. Sci. Technol. 20 (2009)

In this paper, the sensitivity of a quartz crystal microbalance (QCM) sensor is analysed and discussed in terms of the phase change versus the surface mass change, instead of the classical sensitivity in terms of the resonant frequency change derived from the well-known Sauerbrey equation. The detection sensitivity derived from the Sauerbrey equation is a theoretical detection capability in terms of the frequency change versus the mass change, which increases with the square of frequency. However, when a specific application and measuring system are considered, the detection capability of the QCM sensor must be considered from a different point of view. A new equation is obtained, which quantifies the phase shift of a fixed frequency signal corresponding to the series resonant frequency of the sensor in a reference state versus a change in the coating mass, where η_q  is the loss viscosity of the unperturbed sensor and ν_q is the wave propagation speed in quartz, is a parameter which only depends on the physical parameters of the unperturbed resonator and fixes the maximum sensitivity of the sensor and m_L = ρ_Lδ_L/ 2,  where ρ_L  and δ_L are, respectively, the liquid density and the wave penetration depth of the wave in the liquid, is the equivalent surface mass density associated with the oscillatory movement of the surface of the sensor in contact with a fluid medium. This equation is an approximate equation around the series resonance frequency of the sensor. The simulation results for 10, 50 and 150 MHz resonance frequency QCM sensors probe its validity. A new electronic system is proposed for QCM biosensor applications based on the equation introduced.